Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 43, 2016
Previous Article Next Article

Copper-based energetic MOFs with 3-nitro-1H-1,2,4-triazole: solvent-dependent syntheses, structures and energetic performances

Author affiliations

Abstract

The persistent challenge in the field of energetic materials is how to synthesize energetic compounds with high density, high heat of detonation and outstanding detonation performance by gathering the maximum number of energetic groups in the smallest volume. The self-assembly of energetic groups with metal ions is crucially influenced by the solvent conditions. Here, the reaction of Cu(NO3)2·3H2O with 3-nitro-1H-1,2,4-triazole (Hntz) in aqueous ammonia under hydrothermal conditions via a self-assembly strategy yielded the Cu(I) energetic compound [Cu(ntz)]n (1). In order to further enhance the energetic property, an N3 anion was introduced into the system and two Cu(II) energetic compounds, [Cu(ntz)(N3)(DMF)]n (2) and [Cu(ntz)(N3)(H2O)]n (3), were successfully synthesized under different solvent conditions. Structural analyses show that compound 1 features a compacted 3D structure framework and compounds 2–3 exhibit 1D butterfly-like chain structures. The experimental results reveal that 1 possesses attractive thermal stability up to 315.0 °C and 1–3 present excellent insensitivity. Importantly, the heat of detonation of compound 2 has been factually improved due to the abundant energetic bonds in the coordinated DMF molecules compared to 1 and lots of energies are taken away during the release of the coordinated solvent molecules in the low temperature range resulting in the obvious decreases in detonation pressure and detonation velocity for compounds 2–3, which further exemplifies that the subtle change of reaction conditions may have a crucial effect on the resultant detonation performance. In addition, the detonation performances of 1–3 calculated by both a simple method for metal-containing explosives developed by Pang et al. and the commercial program EXPLO5 v6.01, are discussed in detail.

Graphical abstract: Copper-based energetic MOFs with 3-nitro-1H-1,2,4-triazole: solvent-dependent syntheses, structures and energetic performances

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 19 Sep 2016, accepted on 02 Oct 2016 and first published on 03 Oct 2016


Article type: Paper
DOI: 10.1039/C6DT03631G
Citation: Dalton Trans., 2016,45, 17304-17311
  •   Request permissions

    Copper-based energetic MOFs with 3-nitro-1H-1,2,4-triazole: solvent-dependent syntheses, structures and energetic performances

    X. Qu, L. Zhai, B. Wang, Q. Wei, G. Xie, S. Chen and S. Gao, Dalton Trans., 2016, 45, 17304
    DOI: 10.1039/C6DT03631G

Search articles by author