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Issue 42, 2016
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Deuterium substitution effects on the structural and magnetic phase transitions of a hydrogen-bonded coordination polymer, bis(glycolato)copper(II)

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Abstract

Bis(glycolato)copper(II) [Cu(HOCH2CO2)2] shows a structural phase transition around 220 K under cooling and 270 K under heating, and ferromagnetic ordering at 1.1 K. Deuterium substitution of the hydroxyl groups in it induced a large shift in the structural transition temperature while no shift in the ferromagnetic transition temperature took place.

Graphical abstract: Deuterium substitution effects on the structural and magnetic phase transitions of a hydrogen-bonded coordination polymer, bis(glycolato)copper(ii)

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Publication details

The article was received on 15 Sep 2016, accepted on 30 Sep 2016 and first published on 03 Oct 2016


Article type: Communication
DOI: 10.1039/C6DT03592B
Citation: Dalton Trans., 2016,45, 16774-16778
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    Deuterium substitution effects on the structural and magnetic phase transitions of a hydrogen-bonded coordination polymer, bis(glycolato)copper(II)

    S. Yoneyama, T. Kodama, K. Kikuchi, T. Fujisawa, A. Yamaguchi, A. Sumiyama, Y. Shuku, S. Aoyagi and W. Fujita, Dalton Trans., 2016, 45, 16774
    DOI: 10.1039/C6DT03592B

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