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Issue 42, 2016
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Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

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Abstract

Cobalt–iron Prussian blue analogues are magnetic functional compounds that exhibit charge-transfer-induced spin transition (CTIST), however, the role of guest species such as water in influencing the magnetic behaviour has remained unclear. Here, we report the water-dependent CTIST behaviour of Na0.46Co[Fe(CN)6]0.78(H2O)1.31 together with its single crystal X-ray structural analysis, for the first time.

Graphical abstract: Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

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Publication details

The article was received on 06 Sep 2016, accepted on 29 Sep 2016 and first published on 30 Sep 2016


Article type: Communication
DOI: 10.1039/C6DT03474H
Citation: Dalton Trans., 2016,45, 16784-16788
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    Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

    H. Ohmagari, R. Ohtani, M. Nakaya, M. Ohba, M. Nakamura, L. F. Lindoy, O. Sato and S. Hayami, Dalton Trans., 2016, 45, 16784
    DOI: 10.1039/C6DT03474H

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