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Issue 43, 2016
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Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

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Abstract

A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.

Graphical abstract: Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

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Publication details

The article was received on 01 Sep 2016, accepted on 12 Oct 2016, published on 19 Oct 2016 and first published online on 19 Oct 2016


Article type: Communication
DOI: 10.1039/C6DT03416K
Citation: Dalton Trans., 2016,45, 17104-17107
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    Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

    R. Wei, R. Nakahara, J. M. Cameron, G. N. Newton, T. Shiga, H. Sagayama, R. Kumai, Y. Murakami and H. Oshio, Dalton Trans., 2016, 45, 17104
    DOI: 10.1039/C6DT03416K

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