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Issue 41, 2016
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“CLICKable” azide-functionalized phosphonates for the surface-modification of molecular and solid-state metal oxides

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Abstract

The covalent functionalization of metal oxide surfaces with organic ligands gives unique organic–inorganic hybrids. Here we report a bifunctional organic tether combining a phosphonate for metal oxide anchoring with an organic azide for attachment of organic groups. Stable binding of the tether to molecular and solid-state metal oxides is demonstrated and the subsequent “CLICKability” of the TiO2-anchored tether is shown. The phosphonate-azide reported could in future allow the general linkage of functional organic groups to metal oxides.

Graphical abstract: “CLICKable” azide-functionalized phosphonates for the surface-modification of molecular and solid-state metal oxides

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Publication details

The article was received on 29 Aug 2016, accepted on 05 Sep 2016 and first published on 06 Sep 2016


Article type: Communication
DOI: 10.1039/C6DT03370A
Citation: Dalton Trans., 2016,45, 16121-16124
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    “CLICKable” azide-functionalized phosphonates for the surface-modification of molecular and solid-state metal oxides

    S. Schönweiz, S. Knoll, M. Anjass, M. Braumüller, S. Rau and C. Streb, Dalton Trans., 2016, 45, 16121
    DOI: 10.1039/C6DT03370A

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