Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 43, 2016
Previous Article Next Article

A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores

Author affiliations

Abstract

A film of [Pd(R2pipdt)(dmit)] (1), where R2pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the class of dithione–dithiolate 2nd order NLO-chromophores. Moreover full characterization of 1, including molecular second-order NLO properties in solution, is reported.

Graphical abstract: A nonlinear optical active polymer film based on Pd(ii) dithione/dithiolate second-order NLO chromophores

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 22 Jul 2016, accepted on 28 Sep 2016 and first published on 28 Sep 2016


Article type: Paper
DOI: 10.1039/C6DT02911F
Citation: Dalton Trans., 2016,45, 17431-17438
  •   Request permissions

    A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores

    D. Espa, L. Pilia, L. Marchiò, F. Artizzu, G. Di Carlo, D. Marinotto, A. Serpe, F. Tessore and P. Deplano, Dalton Trans., 2016, 45, 17431
    DOI: 10.1039/C6DT02911F

Search articles by author