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Issue 42, 2016
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A propeller-shaped μ4-carbonate hexanuclear dysprosium complex with a high energetic barrier to magnetisation relaxation

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Abstract

A Dy6 complex composed of two Dy3 triangular units, [Dy63-OH)(CO3)3(bsc)3(MeOH)14(H2O)](Cl)5·(H2O)·(MeOH)2 (1), was isolated and found to exhibit slow relaxation of the magnetisation under zero applied dc field, resulting in a high energetic barrier to relaxation.

Graphical abstract: A propeller-shaped μ4-carbonate hexanuclear dysprosium complex with a high energetic barrier to magnetisation relaxation

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Publication details

The article was received on 20 Jul 2016, accepted on 22 Sep 2016 and first published on 23 Sep 2016


Article type: Communication
DOI: 10.1039/C6DT02873J
Citation: Dalton Trans., 2016,45, 16769-16773
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    A propeller-shaped μ4-carbonate hexanuclear dysprosium complex with a high energetic barrier to magnetisation relaxation

    R. J. Holmberg, C. Kuo, B. Gabidullin, C. Wang, R. Clérac, M. Murugesu and P. Lin, Dalton Trans., 2016, 45, 16769
    DOI: 10.1039/C6DT02873J

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