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Issue 42, 2016
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A symmetric, triply interlaced 3-D anionic MOF that exhibits both magnetic order and SMM behaviour

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Abstract

A newly prepared 3-D polymer of cobalt citrate cubanes bridged by high-spin Co(II) centres displays both single-molecule magnet (SMM) behaviour and magnetic ordering. Triple interpenetration of the 3-D diamondoid polymers yields a crystalline solid with channels that host cations and free water molecules, with the SMM behaviour of the Co4O4 cores preserved. The octahedrally coordinated Co(II) bridges are implicated in the onset of magnetic order at an experimentally accessible temperature.

Graphical abstract: A symmetric, triply interlaced 3-D anionic MOF that exhibits both magnetic order and SMM behaviour

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Publication details

The article was received on 04 Jul 2016, accepted on 21 Aug 2016 and first published on 22 Aug 2016


Article type: Communication
DOI: 10.1039/C6DT02652D
Citation: Dalton Trans., 2016,45, 16764-16768
  • Open access: Creative Commons BY-NC license
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    A symmetric, triply interlaced 3-D anionic MOF that exhibits both magnetic order and SMM behaviour

    J. Campo, L. R. Falvello, E. Forcén-Vázquez, C. Sáenz de Pipaón, F. Palacio and M. Tomás, Dalton Trans., 2016, 45, 16764
    DOI: 10.1039/C6DT02652D

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