Jump to main content
Jump to site search

Issue 46, 2016
Previous Article Next Article

Recyclable scavengers for photo-cyclopropanation via an in situ crystallization process

Author affiliations

Abstract

The palladium(II) cyclophane systems, constructed by previously reported proof-of-concept self-assembly, represent a crucial landmark in the field of effective and recyclable scavenging of triiodide (I3) in the photo-cyclopropanation of alkenes with CH2I2. The scavenger's driving force behind photo-cyclopropanation is the efficient in situ crystallization of triiodide-exchanged species. The exact quantitative photoreaction yields according to the mole ratios of the cyclophane system are impressive. The recycling behavior can be ascribed to the rigidity and stability of the four-layered tripalladium(II)cyclophane.

Graphical abstract: Recyclable scavengers for photo-cyclopropanation via an in situ crystallization process

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 30 Jun 2016, accepted on 19 Sep 2016, published on 19 Sep 2016 and first published online on 19 Sep 2016


Article type: Paper
DOI: 10.1039/C6DT02604D
Citation: Dalton Trans., 2016,45, 18476-18483
  •   Request permissions

    Recyclable scavengers for photo-cyclopropanation via an in situ crystallization process

    H. Lee, E. Choi, T. H. Noh and O. Jung, Dalton Trans., 2016, 45, 18476
    DOI: 10.1039/C6DT02604D

Search articles by author