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Issue 43, 2016
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syn-Bimane as a chelating O-donor ligand for palladium(II)

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Abstract

A cationic Pd(II) complex containing syn-(Me,Me)bimane as a ligand was prepared and fully characterized. This complex represents the first well-defined case of a bimane scaffold coordinated to a metal center. The strongly-fluorescent syn-bimane chelates the Pd(II) center via its carbonyl oxygen atoms, affording a non-fluorescent complex. The crystal structure of this complex shows that the coordinated bimane departs from planarity, with its bicyclic framework bent about the N–N bond. Spectroscopic evidence demonstrates that bimane coordination is reversible in solution.

Graphical abstract: syn-Bimane as a chelating O-donor ligand for palladium(ii)

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Publication details

The article was received on 28 May 2016, accepted on 13 Jul 2016 and first published on 13 Jul 2016


Article type: Paper
DOI: 10.1039/C6DT02141G
Citation: Dalton Trans., 2016,45, 17123-17131
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    syn-Bimane as a chelating O-donor ligand for palladium(II)

    P. J. Das, Y. Diskin-Posner, M. Firer, M. Montag and F. Grynszpan, Dalton Trans., 2016, 45, 17123
    DOI: 10.1039/C6DT02141G

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