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Issue 42, 2016
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[BEDT-TTF][Fe(C2O4)Cl2]: an organic–inorganic hybrid semiconductive antiferromagnet

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A radical cation salt composed of an organic donor, BEDT-TTF1.0+, and a one-dimensional inorganic anion, [Fe(C2O4)Cl2]n, was obtained by electrocrystallization, and was identified as a semiconductor with values of σ300K = 3.0 × 10−5 S cm−1. Spin-canted antiferromagnetic long-range ordering was observed at 5.5 K from ZFCM/FCM/RM measurement and confirmed using AC measurement.

Graphical abstract: [BEDT-TTF][Fe(C2O4)Cl2]: an organic–inorganic hybrid semiconductive antiferromagnet

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Publication details

The article was received on 10 May 2016, accepted on 16 Jun 2016 and first published on 17 Jun 2016

Article type: Communication
DOI: 10.1039/C6DT01845A
Citation: Dalton Trans., 2016,45, 16561-16565
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    [BEDT-TTF][Fe(C2O4)Cl2]: an organic–inorganic hybrid semiconductive antiferromagnet

    B. Zhang, Y. Zhang, Z. Wang, D. Yang, Z. Gao, D. Wang, Y. Guo, D. Zhu and T. Mori, Dalton Trans., 2016, 45, 16561
    DOI: 10.1039/C6DT01845A

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