Issue 28, 2016
From the journal:

Dalton Transactions

Spatial aromatic fences of metal–organic frameworks for manipulating the electron spin of a fulleropyrrolidine nitroxide radical†

Jiamei Cao,ac   Yongqiang Feng,*a   Shengju Zhou,ac   Xiaofeng Sun,ac   Taishan Wang,b   Chunru Wangb  and  Hongguang Li*a  

* Corresponding authors

a State Key Laboratory of Solid Lubrication & Laboratory of Clean Energy Chemistry and Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
E-mail: fengyq@licp.cas.cn, hgli@licp.cas.cn

b Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

c University of Chinese Academy of Sciences, Beijing, China

Abstract

The electron spin properties of a fulleropyrrolidine nitroxide radical incarcerated in the pores of MOF-177 and MIL-53 respectively were investigated for the first time. It was found that the spatial confinement effect and intramolecular interactions in these two solid-state spin systems lead to dramatically distinctive spin dynamics.

Graphical abstract: Spatial aromatic fences of metal–organic frameworks for manipulating the electron spin of a fulleropyrrolidine nitroxide radical

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Article information

DOI
https://doi.org/10.1039/C6DT01735E
Article type
Communication
Submitted
03 May 2016
Accepted
20 Jun 2016
First published
20 Jun 2016

Dalton Trans., 2016,45, 11272-11276

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Spatial aromatic fences of metal–organic frameworks for manipulating the electron spin of a fulleropyrrolidine nitroxide radical

J. Cao, Y. Feng, S. Zhou, X. Sun, T. Wang, C. Wang and H. Li, Dalton Trans., 2016, 45, 11272 DOI: 10.1039/C6DT01735E

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