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Issue 31, 2016
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Ferromagnetic coupling mediated by Co⋯π non-covalent contacts in a pentacoordinate Co(II) compound showing field-induced slow relaxation of magnetization

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Abstract

[CoII(dpt)(NCS)2], where dpt = bis(3-aminopropyl)amine, was identified as a pentacoordinate CoII compound showing field-induced slow relaxation of magnetization. Furthermore, intermolecular ferromagnetic coupling mediated by Co⋯π non-covalent contacts, where π orbitals originate from the thiocyanato ligand, is reported for the first time.

Graphical abstract: Ferromagnetic coupling mediated by Co⋯π non-covalent contacts in a pentacoordinate Co(ii) compound showing field-induced slow relaxation of magnetization

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Publication details

The article was received on 21 Apr 2016, accepted on 12 Jul 2016 and first published on 12 Jul 2016


Article type: Paper
DOI: 10.1039/C6DT01539E
Citation: Dalton Trans., 2016,45, 12479-12482
  • Open access: Creative Commons BY-NC license
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    Ferromagnetic coupling mediated by Co⋯π non-covalent contacts in a pentacoordinate Co(II) compound showing field-induced slow relaxation of magnetization

    I. Nemec, R. Herchel and Z. Trávníček, Dalton Trans., 2016, 45, 12479
    DOI: 10.1039/C6DT01539E

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