Issue 25, 2016
From the journal:

Dalton Transactions

Stabilization of molecular lanthanide polysulfides by bulky scorpionate ligands†‡

Marcel Kühling,a   Robert McDonald,b   Phil Liebing,a   Liane Hilfert,a   Michael J. Ferguson,b   Josef Takats*b  and  Frank T. Edelmann*a  

* Corresponding authors

a Chemisches Institut der Otto-von-Guericke-Universität, 39106 Magdeburg, Germany
E-mail: frank.edelmann@ovgu.de

b Department of Chemistry, University of Alberta, Edmonton, Alberta, AB, Canada T6G 2G2
E-mail: joe.takats@ualberta.ca

Abstract

Well-defined lanthanide polysulfide complexes containing S42− and S52− ligands, the samarium(III) pentasulfide complex Sm(TpiPr2)(κ1-3,5-iPr2Hpz)(S5) and the tetrasulfide-bridged binuclear ytterbium(III) complex (μ-S4)[Yb(TpiPr2)(κ1-3,5-iPr2Hpz)(κ2-3,5-iPr2pz)]2 (TpiPr2 = hydro-tris(3,5-diisopropylpyrazolyl)borate), have been synthesized and structurally characterized by single-crystal X-ray diffraction.

Graphical abstract: Stabilization of molecular lanthanide polysulfides by bulky scorpionate ligands

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Article information

DOI
https://doi.org/10.1039/C6DT01439A
Article type
Communication
Submitted
14 Apr 2016
Accepted
28 Apr 2016
First published
28 Apr 2016
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 10118-10121

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Stabilization of molecular lanthanide polysulfides by bulky scorpionate ligands

M. Kühling, R. McDonald, P. Liebing, L. Hilfert, M. J. Ferguson, J. Takats and F. T. Edelmann, Dalton Trans., 2016, 45, 10118 DOI: 10.1039/C6DT01439A

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