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Issue 23, 2016
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A high-nuclearity metal-cyanide cluster [Mo6Cu14] with photomagnetic properties

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Abstract

A high-nuclearity metal-cyanide cluster [Mo6Cu14] has been prepared and its photomagnetic properties investigated. The photoswitchable magnetic phenomenon observed is thermally reversible (T ≈ 230 K). In the field of photomagnetism, [Mo6Cu14] represents a unique example of a nanocage and the highest nuclearity observed so far.

Graphical abstract: A high-nuclearity metal-cyanide cluster [Mo6Cu14] with photomagnetic properties

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Publication details

The article was received on 24 Feb 2016, accepted on 20 Apr 2016 and first published on 27 Apr 2016


Article type: Paper
DOI: 10.1039/C6DT00743K
Citation: Dalton Trans., 2016,45, 9412-9418
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    A high-nuclearity metal-cyanide cluster [Mo6Cu14] with photomagnetic properties

    N. Bridonneau, L.-M. Chamoreau, G. Gontard, J.-L. Cantin, J. von Bardeleben and V. Marvaud, Dalton Trans., 2016, 45, 9412
    DOI: 10.1039/C6DT00743K

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