Issue 16, 2016

Electromagnetic susceptibility anisotropy and its importance for paramagnetic NMR and optical spectroscopy in lanthanide coordination chemistry

Abstract

The importance of the directional dependence of magnetic susceptibility in magnetic resonance and of electric susceptibility in the optical spectroscopy of lanthanide coordination complexes is assessed. A body of more reliable shift, relaxation and optical emission data is emerging for well-defined isostructural series of complexes, allowing detailed comparative analyses to be undertaken. Such work is highlighting the limitations of the current NMR shift and relaxation theories, as well as emphasising the absence of a compelling theoretical framework to explain optical emission phenomena.

Graphical abstract: Electromagnetic susceptibility anisotropy and its importance for paramagnetic NMR and optical spectroscopy in lanthanide coordination chemistry

Article information

Article type
Perspective
Submitted
18 Jan 2016
Accepted
10 Feb 2016
First published
15 Feb 2016

Dalton Trans., 2016,45, 6782-6800

Author version available

Electromagnetic susceptibility anisotropy and its importance for paramagnetic NMR and optical spectroscopy in lanthanide coordination chemistry

O. A. Blackburn, R. M. Edkins, S. Faulkner, A. M. Kenwright, D. Parker, N. J. Rogers and S. Shuvaev, Dalton Trans., 2016, 45, 6782 DOI: 10.1039/C6DT00227G

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