Issue 4, 2016
From the journal:

Dalton Transactions

Homochiral and heterochiral Mn(ii) coordination frameworks: spontaneous resolution dependent on dipyridyl ligands†

Qi Yue,*a   Na-Na Wang,a   Shao-Yun Guo,a   Lu-Lu Lianga  and  En-Qing Gao*a  

* Corresponding authors

a School of Chemistry and Molecular Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai, People's Republic of China
E-mail: qyue@chem.ecnu.edu.cn
Fax: +86-21-54340062

Abstract

An unsymmetric tetracarboxylic ligand collaborates with 4,4′-bipyridine to induce spontaneous resolution to form homochiral 3D coordination frameworks, while the use of longer dipyridyl ligands instead of 4,4′-bipyridine leads to isoreticular but heterochiral frameworks.

Graphical abstract: Homochiral and heterochiral Mn(ii) coordination frameworks: spontaneous resolution dependent on dipyridyl ligands

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Article information

DOI
https://doi.org/10.1039/C5DT04385A
Article type
Communication
Submitted
06 Nov 2015
Accepted
22 Dec 2015
First published
23 Dec 2015

Dalton Trans., 2016,45, 1335-1338

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Homochiral and heterochiral Mn(II) coordination frameworks: spontaneous resolution dependent on dipyridyl ligands

Q. Yue, N. Wang, S. Guo, L. Liang and E. Gao, Dalton Trans., 2016, 45, 1335 DOI: 10.1039/C5DT04385A

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