Issue 1, 2016
From the journal:

Dalton Transactions

Hydrogen atom transfer reactions of ferrate(vi) with phenols and hydroquinone. Correlation of rate constants with bond strengths and application of the Marcus cross relation†

Jianhui Xie,a   Li Ma,a   William W. Y. Lam,a   Kai-Chung Laua  and  Tai-Chu Lau*a  

* Corresponding authors

a Department of Biology and Chemistry, City University of Hong Kong, Tat Chee, Avenue, Kowloon Tong, Hong Kong, People's Republic of China
E-mail: bhtclau@cityu.edu.hk

Abstract

The oxidation of phenols by HFeO4− proceeds via a hydrogen atom transfer (HAT) mechanism, as evidenced by a large deuterium isotope effect and a linear correlation between the log(rate constant) and bond dissociation free energy (BDFE) of phenols. The Marcus cross relation has been applied to predict the rate constant of HAT from hydroquinone to HFeO4−.

Graphical abstract: Hydrogen atom transfer reactions of ferrate(vi) with phenols and hydroquinone. Correlation of rate constants with bond strengths and application of the Marcus cross relation

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Article information

DOI
https://doi.org/10.1039/C5DT04303D
Article type
Communication
Submitted
02 Nov 2015
Accepted
13 Nov 2015
First published
13 Nov 2015

Dalton Trans., 2016,45, 70-73

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Hydrogen atom transfer reactions of ferrate(VI) with phenols and hydroquinone. Correlation of rate constants with bond strengths and application of the Marcus cross relation

J. Xie, L. Ma, W. W. Y. Lam, K. Lau and T. Lau, Dalton Trans., 2016, 45, 70 DOI: 10.1039/C5DT04303D

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