Synthesis and characterization of [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl, Br, I) containing two terminal indium fragments

Masumi Itazaki; Masaki Ito; Satoru Nakashima; Hiroshi Nakazawa

doi:10.1039/C5DT03745J

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Synthesis and characterization of [Fe(NCCH₃)₆][cis-Fe(InX₃)₂(CO)₄] (X = Cl, Br, I) containing two terminal indium fragments†‡

Masumi Itazaki,*^a Masaki Ito,^a Satoru Nakashima^b and Hiroshi Nakazawa*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan
E-mail: mitazaki@sci.osaka-cu.ac.jp, nakazawa@sci.osaka-cu.ac.jp

^b Natural Science Center for Basic Research and Development, Hiroshima University, 1-4-2 Kagamiyama, Higashi-Hiroshima 739-8526, Japan

Abstract

Iron complexes, [Fe(NCCH₃)₆][cis-Fe(InX₃)₂(CO)₄] (X = Cl: 1, Br: 2, I: 3) containing two terminal indium fragments, were synthesized. Their structures were determined using X-ray analysis. The bonding mode of the Fe–In bonds in the anionic part was investigated using ⁵⁷Fe Mössbauer and IR spectroscopy. These complexes represent the first example of transition metal complexes containing two terminal indium fragments.

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DOI: https://doi.org/10.1039/C5DT03745J
Article type: Communication
Submitted: 25 Sep 2015
Accepted: 11 Dec 2015
First published: 24 Dec 2015

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Dalton Trans., 2016,45, 1327-1330

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Synthesis and characterization of [Fe(NCCH₃)₆][cis-Fe(InX₃)₂(CO)₄] (X = Cl, Br, I) containing two terminal indium fragments

M. Itazaki, M. Ito, S. Nakashima and H. Nakazawa, Dalton Trans., 2016, 45, 1327 DOI: 10.1039/C5DT03745J

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