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Issue 10, 2016
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High volumetric uptake of ammonia using Cu-MOF-74/Cu-CPO-27

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Abstract

Cu-MOF-74 (also known as Cu-CPO-27) was identified as a sorbent having one of the highest densities of Cu(II) sites per unit volume. Given that Cu(II) in the framework can be thermally activated to yield a five-coordinate Cu(II) species, we identified this MOF as a potential candidate for maximal volumetric uptake of ammonia. To that end, the kinetic breakthrough of ammonia in Cu-MOF-74/Cu-CPO-27 was examined under both dry and humid conditions. Under dry conditions the MOF exhibited a respectable performance (2.6 vs. 2.9 NH3 per nm3 for the current record holder HKUST-1), and under 80% relative humidity, the MOF outperformed HKUST-1 (5.9 vs. 3.9 NH3 per nm3, respectively).

Graphical abstract: High volumetric uptake of ammonia using Cu-MOF-74/Cu-CPO-27

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Publication details

The article was received on 04 Sep 2015, accepted on 24 Sep 2015 and first published on 24 Sep 2015


Article type: Paper
DOI: 10.1039/C5DT03436A
Citation: Dalton Trans., 2016,45, 4150-4153
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    High volumetric uptake of ammonia using Cu-MOF-74/Cu-CPO-27

    M. J. Katz, A. J. Howarth, P. Z. Moghadam, J. B. DeCoste, R. Q. Snurr, J. T. Hupp and O. K. Farha, Dalton Trans., 2016, 45, 4150
    DOI: 10.1039/C5DT03436A

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