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Issue 9, 2016
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The palladium and copper contrast: a twist to products of different chemotypes and altered mechanistic pathways

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Abstract

A novel contrast in palladium and copper catalysis is revealed to form products of different chemotypes resulting in a phenazine to azoarene twist through an altered mechanistic pathway (from non-radical C–H activation mode of C–N coupling to radical N–N coupling) during the oxidative self-coupling of anilines catalysed by Pd–Ag and Cu–Ag nanoclusters.

Graphical abstract: The palladium and copper contrast: a twist to products of different chemotypes and altered mechanistic pathways

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Publication details

The article was received on 28 Feb 2016, accepted on 27 Mar 2016 and first published on 29 Mar 2016


Article type: Communication
DOI: 10.1039/C6CY00415F
Citation: Catal. Sci. Technol., 2016,6, 2892-2896
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    The palladium and copper contrast: a twist to products of different chemotypes and altered mechanistic pathways

    K. Seth, S. R. Roy, A. Kumar and A. K. Chakraborti, Catal. Sci. Technol., 2016, 6, 2892
    DOI: 10.1039/C6CY00415F

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