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Issue 22, 2016
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Photocatalysis in organic and polymer synthesis

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This review, with over 600 references, summarizes the recent applications of photoredox catalysis for organic transformation and polymer synthesis. Photoredox catalysts are metallo- or organo-compounds capable of absorbing visible light, resulting in an excited state species. This excited state species can donate or accept an electron from other substrates to mediate redox reactions at ambient temperature with high atom efficiency. These catalysts have been successfully implemented for the discovery of novel organic reactions and synthesis of added-value chemicals with an excellent control of selectivity and stereo-regularity. More recently, such catalysts have been implemented by polymer chemists to post-modify polymers in high yields, as well as to effectively catalyze reversible deactivation radical polymerizations and living polymerizations. These catalysts create new approaches for advanced organic transformation and polymer synthesis. The objective of this review is to give an overview of this emerging field to organic and polymer chemists as well as materials scientists.

Graphical abstract: Photocatalysis in organic and polymer synthesis

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The article was received on 07 Mar 2016 and first published on 12 May 2016

Article type: Review Article
DOI: 10.1039/C6CS00185H
Citation: Chem. Soc. Rev., 2016,45, 6165-6212
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    Photocatalysis in organic and polymer synthesis

    N. Corrigan, S. Shanmugam, J. Xu and C. Boyer, Chem. Soc. Rev., 2016, 45, 6165
    DOI: 10.1039/C6CS00185H

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