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Issue 28, 2016
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Molecular design of light-harvesting photosensitizers: effect of varied linker conjugation on interfacial electron transfer

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Abstract

Interfacial electron transfer dynamics of a series of photosensitizers bound to TiO2via linkers of varying conjugation strength are explored by spectroscopic and computational techniques. Injection and recombination depend on the extent of conjugation in the linker, where the LUMO delocalization determines the injection dynamics but both the HOMO and HOMO−1 are involved in recombination.

Graphical abstract: Molecular design of light-harvesting photosensitizers: effect of varied linker conjugation on interfacial electron transfer

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Publication details

The article was received on 30 May 2016, accepted on 23 Jun 2016 and first published on 30 Jun 2016


Article type: Communication
DOI: 10.1039/C6CP04377A
Citation: Phys. Chem. Chem. Phys., 2016,18, 18678-18682
  • Open access: Creative Commons BY-NC license
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    Molecular design of light-harvesting photosensitizers: effect of varied linker conjugation on interfacial electron transfer

    J. Jiang, J. R. Swierk, S. Hedström, A. J. Matula, R. H. Crabtree, V. S. Batista, C. A. Schmuttenmaer and G. W. Brudvig, Phys. Chem. Chem. Phys., 2016, 18, 18678
    DOI: 10.1039/C6CP04377A

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