Issue 26, 2016
From the journal:

Physical Chemistry Chemical Physics

Fabrication of bilayer tetrathiafulvalene integrated surface covalent organic frameworks†

Wei-Long Dong,ab   Shu-Ying Li,ab   Jie-Yu Yue,ab   Cheng Wang,c   Dong Wang*a  and  Li-Jun Wan*a  

* Corresponding authors

a Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, P. R. China
E-mail: wangd@iccas.ac.cn, wanlijun@iccas.ac.cn

b University of CAS, Beijing, P. R. China

c Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China

Abstract

A bilayer covalent organic framework (COF) of TTF-based building blocks was obtained by imine reaction between tetrathiafulvalene tetraaldehyde (4ATTF) and p-phenylenediamine (PPDA). Direct evidence for the eclipsed stacking of bilayer structure via π–π interaction between TTF units is provided by high resolution scanning tunneling microscopy.

Graphical abstract: Fabrication of bilayer tetrathiafulvalene integrated surface covalent organic frameworks

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Article information

DOI
https://doi.org/10.1039/C6CP01804A
Article type
Communication
Submitted
17 Mar 2016
Accepted
06 Jun 2016
First published
06 Jun 2016

Phys. Chem. Chem. Phys., 2016,18, 17356-17359

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Fabrication of bilayer tetrathiafulvalene integrated surface covalent organic frameworks

W. Dong, S. Li, J. Yue, C. Wang, D. Wang and L. Wan, Phys. Chem. Chem. Phys., 2016, 18, 17356 DOI: 10.1039/C6CP01804A

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