Issue 7, 2016

Coherent vibration and ultrafast dynamics upon bond formation in excited dimers of an Au(i) complex

Abstract

Au–Au bond strengthening in photoexcited dimers of an Au(I) complex is captured in solution as oscillations of femtosecond absorption signals. The subsequent dynamics, when compared to the trimer's data, confirm that the bent-to-linear structural change of the trimer occurs in the first few picoseconds.

Graphical abstract: Coherent vibration and ultrafast dynamics upon bond formation in excited dimers of an Au(i) complex

Supplementary files

Article information

Article type
Communication
Submitted
02 Nov 2015
Accepted
19 Jan 2016
First published
19 Jan 2016

Phys. Chem. Chem. Phys., 2016,18, 5103-5107

Author version available

Coherent vibration and ultrafast dynamics upon bond formation in excited dimers of an Au(I) complex

M. Iwamura, R. Wakabayashi, J. Maeba, K. Nozaki, S. Takeuchi and T. Tahara, Phys. Chem. Chem. Phys., 2016, 18, 5103 DOI: 10.1039/C5CP06651D

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