Issue 2, 2017
From the journal:

CrystEngComm

Two cage-based zinc-tetracarboxylate frameworks with white-light emission†

Qipeng Li, ORCID logo a   Jiagang Luo,a   Lei Wang,a   Cen Qi,a   Yongsheng Yang,a   Xinjun Zhanga  and  Jinjie Qian ORCID logo *b  

* Corresponding authors

a College of Chemistry and Life Science, Zhaotong University, Zhaotong 657000, P. R. China

b College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China
E-mail: jinjieqian@wzu.edu.cn

Abstract

Two novel zinc-tetracarboxylate frameworks (FJI-8 and FJI-9) were solvothermally synthesized and structurally characterized. The 3D cage-stacking frameworks of FJI-8 and FJI-9 are each constructed of a truncated octahedral cage composed of {Zn2(COO)4} paddlewheel SBUs and abtc4− ligands. Eight surrounding octahedral cages create an inner cuboctahedral cavity. In addition, both FJI-8 and FJI-9 exhibit tunable luminescence and white-light emission via varying the excitation wavelength.

Graphical abstract: Two cage-based zinc-tetracarboxylate frameworks with white-light emission

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Article information

DOI
https://doi.org/10.1039/C6CE02281B
Article type
Communication
Submitted
31 Oct 2016
Accepted
07 Dec 2016
First published
07 Dec 2016

CrystEngComm, 2017,19, 214-217

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Two cage-based zinc-tetracarboxylate frameworks with white-light emission

Q. Li, J. Luo, L. Wang, C. Qi, Y. Yang, X. Zhang and J. Qian, CrystEngComm, 2017, 19, 214 DOI: 10.1039/C6CE02281B

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