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Issue 43, 2016
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Ligand-oriented assembly of a porous metal–organic framework by [CuI4I4] clusters and paddle-wheel [CuII2(COO)4(H2O)2] subunits

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Abstract

A novel porous mixed-valence copper–organic framework based on CuI4I4 clusters and paddle-wheel [CuII2(COO)4(H2O)2] moieties was synthesized through a ligand-oriented assembly. The mixed-valence Cu(I)–Cu(II) complex features the coexistence of micro-sized cages and 1D channels and its sorption behaviour has been investigated.

Graphical abstract: Ligand-oriented assembly of a porous metal–organic framework by [CuI4I4] clusters and paddle-wheel [CuII2(COO)4(H2O)2] subunits

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Publication details

The article was received on 08 Sep 2016, accepted on 23 Sep 2016 and first published on 23 Sep 2016


Article type: Communication
DOI: 10.1039/C6CE01954D
Citation: CrystEngComm, 2016,18, 8362-8365
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    Ligand-oriented assembly of a porous metal–organic framework by [CuI4I4] clusters and paddle-wheel [CuII2(COO)4(H2O)2] subunits

    G. Wang, Z. Xue, J. Pan, L. Wei, S. Han, J. Qian and Z. Wang, CrystEngComm, 2016, 18, 8362
    DOI: 10.1039/C6CE01954D

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