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Issue 46, 2016
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Ring size effect on the solid state assembly of propargyl substituted hexa- and octacyclic peptoids

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Abstract

The investigation of the solid state assembly of propargyl substituted hexa- and octacyclic peptoids highlights the effect of ring size in determining the packing arrangement of the macrocycles. A layered arrangement is obtained in the case of the hexacyclic peptoid 1 and a tubular arrangement in the case of the octacyclic peptoid 2. Guest molecules either intercalate between the layers as in 1 or are located within the peptoid nanotube as in 2.

Graphical abstract: Ring size effect on the solid state assembly of propargyl substituted hexa- and octacyclic peptoids

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Publication details

The article was received on 18 Aug 2016, accepted on 22 Sep 2016 and first published on 23 Sep 2016


Article type: Paper
DOI: 10.1039/C6CE01800A
Citation: CrystEngComm, 2016,18, 8838-8848
  • Open access: Creative Commons BY-NC license
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    Ring size effect on the solid state assembly of propargyl substituted hexa- and octacyclic peptoids

    C. Tedesco, A. Meli, E. Macedi, V. Iuliano, A. G. Ricciardulli, F. De Riccardis, G. B. M. Vaughan, V. J. Smith, L. J. Barbour and I. Izzo, CrystEngComm, 2016, 18, 8838
    DOI: 10.1039/C6CE01800A

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