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Issue 46, 2016
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Absolute asymmetric synthesis of a sanguinarine derivative through crystal–solution interactions

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Abstract

A new construction reaction for the absolute asymmetric synthesis of a sanguinarine derivative was realized by crystal–solution interactions. A stochastic outcome with high enantiomeric excess (ee%) values (up to 100%) was observed under cooling crystallization, while preferential chiral amplification was observed with Viedma ripening.

Graphical abstract: Absolute asymmetric synthesis of a sanguinarine derivative through crystal–solution interactions

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Publication details

The article was received on 12 Aug 2016, accepted on 29 Sep 2016 and first published on 29 Sep 2016


Article type: Communication
DOI: 10.1039/C6CE01765G
Citation: CrystEngComm, 2016,18, 8834-8837
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    Absolute asymmetric synthesis of a sanguinarine derivative through crystal–solution interactions

    Q. Zhang, L. Jia, J. Wang and X. Mei, CrystEngComm, 2016, 18, 8834
    DOI: 10.1039/C6CE01765G

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