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Issue 43, 2016
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A unique (3,10)-connected magnesium/nickel-based metal–organic framework constructed from an unusual kgd supermolecular building layer via mixed linkers and solid solution approach

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Abstract

A hydrothermal reaction between mixed linkers and mixed metals, alkaline earth 4MgCO3·Mg(OH)2·5H2O and 3d Ni(CH3COO3)2·4H2O, resulted in a unique metal–organic framework of SNNU-99 that was impressively isolated and structurally characterized. SNNU-99 was constructed from an unprecedented decanuclear Mg/Ni-based secondary building unit and represents the first (3,10)-connected 3-period net. Alternatively, SNNU-99 can be described through an unusual kgd layer pillared through 2-connected linkers. Due to its specifically structural feature, SNNU-99 has demonstrated selective CO2 adsorption over N2.

Graphical abstract: A unique (3,10)-connected magnesium/nickel-based metal–organic framework constructed from an unusual kgd supermolecular building layer via mixed linkers and solid solution approach

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Publication details

The article was received on 24 Jul 2016, accepted on 13 Sep 2016 and first published on 14 Sep 2016


Article type: Communication
DOI: 10.1039/C6CE01629D
Citation: CrystEngComm, 2016,18, 8358-8361
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    A unique (3,10)-connected magnesium/nickel-based metal–organic framework constructed from an unusual kgd supermolecular building layer via mixed linkers and solid solution approach

    Y. Geng, A. Zhang, K. Wu, D. Xue and Z. Liu, CrystEngComm, 2016, 18, 8358
    DOI: 10.1039/C6CE01629D

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