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Issue 42, 2016
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Two novel eight-connected self-penetrating porous lanthanide–organic frameworks: structures, luminescence, and gas adsorption properties

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Abstract

Two novel luminescent three-dimensional coordination polymers [Eu2(tpphz)(oba)3nH2O (n = 5.5 for 1, n = 3.5 for 2; H2oba = 4,4′-dicarboxydiphenyl ether) have been hydrothermally synthesized by in situ generation of tetrapyrido[3,2-a:2′,3′-c:3′′,2′′-h:2′′′,3′′′-j]phenazine (tpphz) ligand from 2-(4-pyridine)-imidazo-[4,5-f]1,10-phenanthroline precursor. Both complexes are rare examples of eight-connected self-penetrating networks. The porous nature of the structures is further supported by gas adsorption measurements.

Graphical abstract: Two novel eight-connected self-penetrating porous lanthanide–organic frameworks: structures, luminescence, and gas adsorption properties

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Publication details

The article was received on 10 Jul 2016, accepted on 14 Sep 2016 and first published on 15 Sep 2016


Article type: Communication
DOI: 10.1039/C6CE01527A
Citation: CrystEngComm, 2016,18, 8159-8163
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    Two novel eight-connected self-penetrating porous lanthanide–organic frameworks: structures, luminescence, and gas adsorption properties

    D. Qiang, X. Yang, X. Deng and H. Sun, CrystEngComm, 2016, 18, 8159
    DOI: 10.1039/C6CE01527A

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