Issue 5, 2016
From the journal:

CrystEngComm

Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects†

Kieran Griffiths,a   Vassiliki N. Dokorou,a   John Spencer,a   Alaa Abdul-Sada,a   Alfredo Vargas*a  and  George E. Kostakis ORCID logo *a  

* Corresponding authors

a Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ, UK
E-mail: Alfredo.Vargas@sussex.ac.uk, G.Kostakis@sussex.ac.uk

Abstract

This work addresses and enlightens synthetic aspects derived from our effort to systematically construct isoskeletal tetranuclear coordination clusters (CCs) of the general formula [TR2Ln2(LX)4(NO3)2(solv)2] possessing a specific defected dicubane topology, utilizing various substituted Schiff base organic ligands (H2LX) and NiII/CoII and Dy(OTf)3 salts. Our synthetic work is further supported by DFT studies.

Graphical abstract: Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects

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Article information

DOI
https://doi.org/10.1039/C5CE02109J
Article type
Paper
Submitted
28 Oct 2015
Accepted
10 Dec 2015
First published
17 Dec 2015
This article is Open Access
Creative Commons BY license

CrystEngComm, 2016,18, 704-713

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Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects

K. Griffiths, V. N. Dokorou, J. Spencer, A. Abdul-Sada, A. Vargas and G. E. Kostakis, CrystEngComm, 2016, 18, 704 DOI: 10.1039/C5CE02109J

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