Issue 20, 2017

Cu(ii)-catalyzed sulfide construction: both aryl groups utilization of intermolecular and intramolecular diaryliodonium salt

Abstract

A sulfur–iodine exchange protocol of diaryliodonium salts with inorganic sulfur salt was developed. Both aryl groups in the diaryliodonium salt were fully exerted in this transformation. Five- to eight-membered sulfur-containing heterocycles were achieved. Note that [1]benzothieno-[3,2-b][1]benzothiophene (BTBT) (an organic field-effect transistor (OFET) material) and Zaltoprofen were efficiently established through this method.

Graphical abstract: Cu(ii)-catalyzed sulfide construction: both aryl groups utilization of intermolecular and intramolecular diaryliodonium salt

Supplementary files

Article information

Article type
Communication
Submitted
17 Nov 2016
Accepted
20 Dec 2016
First published
21 Dec 2016

Chem. Commun., 2017,53, 2918-2921

Cu(II)-catalyzed sulfide construction: both aryl groups utilization of intermolecular and intramolecular diaryliodonium salt

M. Wang, J. Wei, Q. Fan and X. Jiang, Chem. Commun., 2017, 53, 2918 DOI: 10.1039/C6CC09201B

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