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Issue 88, 2016
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Pre-organization of clefts for Ag–π interactions in Zn(II) bisdipyrrin helicates for the construction of heterometallic networks

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Abstract

Coordination of 2,2′-bisdipyrrin based ligands to Zn(II) cations leads to the formation of binuclear helicates with pre-organized pyrrolic strands as well as peripheral aromatic moieties for Ag–π interactions, thus affording crystalline heterometallic networks upon further interactions with Ag(I) salts without the assistance of additional heteroatom-based coordinating units.

Graphical abstract: Pre-organization of clefts for Ag–π interactions in Zn(ii) bisdipyrrin helicates for the construction of heterometallic networks

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Publication details

The article was received on 23 Sep 2016, accepted on 11 Oct 2016 and first published on 11 Oct 2016


Article type: Communication
DOI: 10.1039/C6CC07754D
Citation: Chem. Commun., 2016,52, 13000-13003
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    Pre-organization of clefts for Ag–π interactions in Zn(II) bisdipyrrin helicates for the construction of heterometallic networks

    S. A. Baudron and M. W. Hosseini, Chem. Commun., 2016, 52, 13000
    DOI: 10.1039/C6CC07754D

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