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Issue 91, 2016
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Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation

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Abstract

Herein we report a water-induced single-crystal to single-crystal transformation that involves the formation of hetero-bimetallic paddlewheel clusters in coordination polymers. Through this transformation, which involves the cleavage and formation of different coordination bonds, two different Cu(II)–Zn(II) and Cu(II)–Ni(II) paddlewheel units exhibiting a 1 : 1 metal ratio were created.

Graphical abstract: Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation

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Publication details

The article was received on 20 Sep 2016, accepted on 21 Oct 2016 and first published on 21 Oct 2016


Article type: Communication
DOI: 10.1039/C6CC07653J
Citation: Chem. Commun., 2016,52, 13397-13400
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    Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation

    J. Albalad, J. Aríñez-Soriano, J. Vidal-Gancedo, V. Lloveras, J. Juanhuix, I. Imaz, N. Aliaga-Alcalde and D. Maspoch, Chem. Commun., 2016, 52, 13397
    DOI: 10.1039/C6CC07653J

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