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Issue 89, 2016
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A visible-light-induced chemoselective radical/oxidative addition domino process to access α-chloro and α-alkoxy aryl ketones

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Abstract

A visible-light-induced radical-triggered chemoselective domino process to access α,α-di-functionalized ketones under mild conditions has been developed. This protocol provides a direct approach to synthesize α-chloro or α-alkoxy aryl ketones based on the electronic properties of the substrates. The reaction can tolerate a variety of functional groups to afford the corresponding products in moderate to good yields.

Graphical abstract: A visible-light-induced chemoselective radical/oxidative addition domino process to access α-chloro and α-alkoxy aryl ketones

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Publication details

The article was received on 06 Sep 2016, accepted on 11 Oct 2016 and first published on 12 Oct 2016


Article type: Communication
DOI: 10.1039/C6CC07272K
Citation: Chem. Commun., 2016,52, 13105-13108
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    A visible-light-induced chemoselective radical/oxidative addition domino process to access α-chloro and α-alkoxy aryl ketones

    T. Niu, D. Jiang, S. Li, B. Ni and L. Wang, Chem. Commun., 2016, 52, 13105
    DOI: 10.1039/C6CC07272K

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