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Issue 89, 2016
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Ritter-type amination of C–H bonds at tertiary carbon centers using iodic acid as an oxidant

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Abstract

The Ritter-type amination of a tertiary C–H bond using iodic acid (HIO3) as an oxidant, in the presence of N-hydroxyphthalimide (NHPI) is reported. This operationally simple method is conducted under metal-free conditions, is scalable, and efficiently provides valuable α-tertiary amine derivatives.

Graphical abstract: Ritter-type amination of C–H bonds at tertiary carbon centers using iodic acid as an oxidant

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Publication details

The article was received on 01 Sep 2016, accepted on 21 Sep 2016 and first published on 22 Sep 2016


Article type: Communication
DOI: 10.1039/C6CC07164C
Citation: Chem. Commun., 2016,52, 13082-13085
  • Open access: Creative Commons BY-NC license
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    Ritter-type amination of C–H bonds at tertiary carbon centers using iodic acid as an oxidant

    K. Kiyokawa, K. Takemoto and S. Minakata, Chem. Commun., 2016, 52, 13082
    DOI: 10.1039/C6CC07164C

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