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Issue 88, 2016
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Intermetal oxygen atom transfer from an FeVO complex to a MnIII complex: an experimental and theoretical approach

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Abstract

Oxygen atom transfer (OAT) reaction between an FeVO complex and a MnIII complex resulted in the eventual formation of their corresponding FeIII and MnVO complexes. The reaction proceeded via an initial fast OAT reaction between the FeVO and MnIII complexes, yielding a half equivalent of a MnVO complex and a μ-oxo bridged FeIV dimer. The dimer regenerated the FeVO species via equilibrium, which then reacted with the remaining MnIII complex to produce another half equivalent of the MnVO complex.

Graphical abstract: Intermetal oxygen atom transfer from an FeVO complex to a MnIII complex: an experimental and theoretical approach

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Publication details

The article was received on 01 Sep 2016, accepted on 10 Oct 2016 and first published on 10 Oct 2016


Article type: Communication
DOI: 10.1039/C6CC07152J
Citation: Chem. Commun., 2016,52, 12968-12971
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    Intermetal oxygen atom transfer from an FeVO complex to a MnIII complex: an experimental and theoretical approach

    S. Hong, S. J. Jang, K. Cho and W. Nam, Chem. Commun., 2016, 52, 12968
    DOI: 10.1039/C6CC07152J

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