Issue 91, 2016
From the journal:

Chemical Communications

Synthesis of a monomolecular anionic FLP complex†

A. W. Kyri,a   R. Kunzmann,a   G. Schnakenburg,a   Z.-W. Qu,b   S. Grimme*b  and  R. Streubel*a  

* Corresponding authors

a Institut for Inorganic Chemistry of the Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Strasse 1, 53121 Bonn, Germany
E-mail: r.streubel@uni-bonn.de

b Mulliken Center of the Rheinische Friedrich-Wilhelms-Universität Bonn, Beringstr. 4, 53115 Bonn, Germany
E-mail: grimme@thch.uni-bonn.de

Abstract

Despite intense research in FLP chemistry, nothing is known about monomolecular anionic FLPs and/or complexes thereof. Herein, synthesis and reaction of the first anionic FLP complex is described using [(OC)5W{(Me3Si)2HCP(H)OLi(12-crown-4)}], Cy2BCl and subsequent deprotonation by KHMDS. The obtained anionic FLP complex reacts readily with CO2 in a concerted manner.

Graphical abstract: Synthesis of a monomolecular anionic FLP complex

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Article information

DOI
https://doi.org/10.1039/C6CC07081G
Article type
Communication
Submitted
29 Aug 2016
Accepted
18 Oct 2016
First published
26 Oct 2016

Chem. Commun., 2016,52, 13361-13364

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Synthesis of a monomolecular anionic FLP complex

A. W. Kyri, R. Kunzmann, G. Schnakenburg, Z.-W. Qu, S. Grimme and R. Streubel, Chem. Commun., 2016, 52, 13361 DOI: 10.1039/C6CC07081G

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