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Issue 87, 2016
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A drastic change in the superhydrophilic crystal porosities of metallosupramolecular structures via a slight change in pH

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Abstract

A unique pH-controlled synthesis of two metallosupramolecular structures from CoIII2AuI3 complex anions and ZnII cations is reported. A dense coordination polymer (porosity ∼13%) was formed at a pH of 5.0, whereas a porous ionic framework (porosity ∼61%) that selectively adsorbs CO2 and H2O was created when the pH was adjusted to 5.5.

Graphical abstract: A drastic change in the superhydrophilic crystal porosities of metallosupramolecular structures via a slight change in pH

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Publication details

The article was received on 24 Aug 2016, accepted on 06 Oct 2016 and first published on 14 Oct 2016


Article type: Communication
DOI: 10.1039/C6CC06943F
Citation: Chem. Commun., 2016,52, 12893-12896
  • Open access: Creative Commons BY-NC license
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    A drastic change in the superhydrophilic crystal porosities of metallosupramolecular structures via a slight change in pH

    S. Surinwong, N. Yoshinari, T. Kojima and T. Konno, Chem. Commun., 2016, 52, 12893
    DOI: 10.1039/C6CC06943F

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