Issue 83, 2016
From the journal:

Chemical Communications

Dioxygen-induced oxidative activation of a P–H bond: radical oxyphosphorylation of alkenes and alkynes toward β-oxy phosphonates†

Pan Peng,a   Qingquan Lu,a   Long Peng,a   Chao Liu,a   Guangyu Wanga  and  Aiwen Lei*ab  

* Corresponding authors

a College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China
E-mail: aiwenlei@whu.edu.cn
Web: http://aiwenlei.whu.edu.cn/Main_Website/

b National Research Center for Carbohydrate Synthesis, Jiangxi Normal University, Nanchang, P. R. China

Abstract

The dioxygen-induced radical oxyphosphorylation of alkenes and alkynes is presented, wherein a P–H bond was activated by molecular oxygen. Various β-oxy phosphonates could be facilely synthesized without the assistance of any transition metals or extra organic initiators. Mechanistic studies showed that HP(O)Ph2 acts as a reductant to accelerate oxyphosphorylation.

Graphical abstract: Dioxygen-induced oxidative activation of a P–H bond: radical oxyphosphorylation of alkenes and alkynes toward β-oxy phosphonates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6CC06881B
Article type
Communication
Submitted
25 Aug 2016
Accepted
14 Sep 2016
First published
14 Sep 2016

Chem. Commun., 2016,52, 12338-12341

Permissions

Request permissions

Dioxygen-induced oxidative activation of a P–H bond: radical oxyphosphorylation of alkenes and alkynes toward β-oxy phosphonates

P. Peng, Q. Lu, L. Peng, C. Liu, G. Wang and A. Lei, Chem. Commun., 2016, 52, 12338 DOI: 10.1039/C6CC06881B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements