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Issue 90, 2016
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Transition-metal-free three-component reaction of cyclopropenes, aldehydes and amines

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Abstract

A transition-metal-free three-component reaction of cyclopropenes, aldehydes and amines is reported. The reaction is a new demonstration of formal [3+2] cycloaddition triggered by ring-opening of cyclopropenes bearing electron-withdrawing substituents. The reaction provides a unique method for the construction of cyclopentene structures.

Graphical abstract: Transition-metal-free three-component reaction of cyclopropenes, aldehydes and amines

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Publication details

The article was received on 16 Aug 2016, accepted on 14 Oct 2016 and first published on 17 Oct 2016


Article type: Communication
DOI: 10.1039/C6CC06743C
Citation: Chem. Commun., 2016,52, 13285-13287
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    Transition-metal-free three-component reaction of cyclopropenes, aldehydes and amines

    H. Zhang, B. Wang, H. Yi, T. Sun, Y. Zhang and J. Wang, Chem. Commun., 2016, 52, 13285
    DOI: 10.1039/C6CC06743C

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