Jump to main content
Jump to site search

Issue 90, 2016
Previous Article Next Article

Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy

Author affiliations

Abstract

We show that optical excitation of radical triplet pair systems can produce a fourfold NMR signal enhancement in solution, without the need for microwave pumping. Development of optical hyperpolarization methods will significantly impact all NMR user groups by boosting sensitivity and reducing signal averaging times.

Graphical abstract: Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy

Back to tab navigation

Supplementary files

Publication details

The article was received on 12 Aug 2016, accepted on 30 Sep 2016 and first published on 30 Sep 2016


Article type: Communication
DOI: 10.1039/C6CC06651H
Citation: Chem. Commun., 2016,52, 13221-13224
  • Open access: Creative Commons BY license
  •   Request permissions

    Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy

    M. W. Dale and C. J. Wedge, Chem. Commun., 2016, 52, 13221
    DOI: 10.1039/C6CC06651H

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements