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Issue 90, 2016
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Regioselective preparation of a bis-pyrazolinofullerene by a macrocyclization reaction

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Abstract

A single isomer of a pyrazolinofullerene bis-adduct was prepared by tether-directed remote functionalization. Specifically, a macrocyclization reaction between C60 and a bis-hydrazone reagent has been carried out to generate a regioisomerically pure fullerene bis-adduct which presents a lower LUMO than pristine C60.

Graphical abstract: Regioselective preparation of a bis-pyrazolinofullerene by a macrocyclization reaction

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Publication details

The article was received on 09 Aug 2016, accepted on 28 Sep 2016 and first published on 28 Sep 2016


Article type: Communication
DOI: 10.1039/C6CC06549J
Citation: Chem. Commun., 2016,52, 13205-13208
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    Regioselective preparation of a bis-pyrazolinofullerene by a macrocyclization reaction

    V. Cuesta, M. Urbani, P. de la Cruz, L. Welte, J. Nierengarten and F. Langa, Chem. Commun., 2016, 52, 13205
    DOI: 10.1039/C6CC06549J

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