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Issue 95, 2016
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Molecular engineered nanomaterials for catalytic hydrogen evolution and oxidation

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Abstract

The active sites of hydrogenases have inspired the design of molecular catalysts for hydrogen evolution and oxidation. In this feature article, we showcase key elements of bio-inspiration before embarking on a tour of a representative series of molecular hydrogen evolving catalysts (HECs) and describing the toolbox available for benchmarking their performances. We then show how such catalysts can be immobilized on conducting substrates to prepare electrode materials active for hydrogen evolution and oxidation with a special emphasis on cobalt diimine–dioxime complexes and DuBois' nickel diphosphine compounds. We finally discuss the optimization required for implementing molecular-engineered materials into operational devices and illustrate how such molecular approaches can be expanded to other fuel-forming processes such as the electrochemical valorisation of carbon dioxide and the oxygen reduction or water oxidation reactions.

Graphical abstract: Molecular engineered nanomaterials for catalytic hydrogen evolution and oxidation

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Publication details

The article was received on 30 Jul 2016, accepted on 06 Sep 2016 and first published on 27 Sep 2016


Article type: Feature Article
DOI: 10.1039/C6CC06311J
Citation: Chem. Commun., 2016,52, 13728-13748
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    Molecular engineered nanomaterials for catalytic hydrogen evolution and oxidation

    N. Coutard, N. Kaeffer and V. Artero, Chem. Commun., 2016, 52, 13728
    DOI: 10.1039/C6CC06311J

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