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Issue 94, 2016
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Palladium-catalyzed dearomative arylalkynylation of indoles

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Abstract

A palladium-catalyzed indole dearomative bisfunctionalization via a domino arylation/alkynylation sequence has been developed, which provides a reliable approach to a series of structurally diverse tetracyclic indolines bearing vicinal tertiary and quaternary stereocenters in moderate to good yields and excellent diastereoselectivities.

Graphical abstract: Palladium-catalyzed dearomative arylalkynylation of indoles

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Publication details

The article was received on 28 Jul 2016, accepted on 29 Sep 2016 and first published on 29 Sep 2016


Article type: Communication
DOI: 10.1039/C6CC06262H
Citation: Chem. Commun., 2016,52, 13664-13667
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    Palladium-catalyzed dearomative arylalkynylation of indoles

    R. Liu, T. Xu, Y. Wang, B. Xiang, J. Gao and Y. Jia, Chem. Commun., 2016, 52, 13664
    DOI: 10.1039/C6CC06262H

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