Jump to main content
Jump to site search

Issue 88, 2016
Previous Article Next Article

Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

Author affiliations

Abstract

Room-temperature accelerated aging in the solid state has been applied for atom- and energy-efficient activation of either one or two C–H bonds of azobenzene and methyl orange by palladium(II) acetate. Organopalladium complexes are prepared in quantitative reactions without potentially harmful side products. Dicyclopalladated methyl orange is water-soluble and is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in buffered aqueous media.

Graphical abstract: Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 22 Jul 2016, accepted on 01 Sep 2016 and first published on 01 Sep 2016


Article type: Communication
DOI: 10.1039/C6CC06062E
Citation: Chem. Commun., 2016,52, 12960-12963
  •   Request permissions

    Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

    A. Monas, K. Užarević, I. Halasz, M. J. Kulcsár and M. Ćurić, Chem. Commun., 2016, 52, 12960
    DOI: 10.1039/C6CC06062E

Search articles by author