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Issue 87, 2016
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Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2−

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The mononuclear complex (Bu4N)2[ReIVCl4(CN)2]·2DMA (DMA = N,N-dimethylacetamide) displays intricate magnetization dynamics, implying Orbach, direct, and Raman-type relaxation processes. The Orbach relaxation process is characterized by an energy barrier of 39 K (27 cm−1) that is discussed based on high-field electron paramagnetic resonance (EPR), inelastic neutron scattering and frequency-domain THz EPR investigations.

Graphical abstract: Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2−

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The article was received on 01 Jul 2016, accepted on 04 Oct 2016 and first published on 05 Oct 2016

Article type: Communication
DOI: 10.1039/C6CC05473K
Citation: Chem. Commun., 2016,52, 12905-12908
  • Open access: Creative Commons BY-NC license
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    Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2−

    X. Feng, J. Liu, K. S. Pedersen, J. Nehrkorn, A. Schnegg, K. Holldack, J. Bendix, M. Sigrist, H. Mutka, D. Samohvalov, D. Aguilà, M. Tong, J. R. Long and R. Clérac, Chem. Commun., 2016, 52, 12905
    DOI: 10.1039/C6CC05473K

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