Issue 66, 2016

Cobalt-catalyzed chelation assisted C–H allylation of aromatic amides with unactivated olefins

Abstract

The cobalt-catalyzed chelation assisted ortho C–H allylation of aromatic amides with unactivated aliphatic alkenes is reported. The reaction proceeds in air under mild reaction conditions, providing allylated products in good to excellent yields with high E-selectivities. This operationally simple method shows a high functional group tolerance.

Graphical abstract: Cobalt-catalyzed chelation assisted C–H allylation of aromatic amides with unactivated olefins

Supplementary files

Article information

Article type
Communication
Submitted
27 Jun 2016
Accepted
15 Jul 2016
First published
18 Jul 2016

Chem. Commun., 2016,52, 10129-10132

Cobalt-catalyzed chelation assisted C–H allylation of aromatic amides with unactivated olefins

T. Yamaguchi, Y. Kommagalla, Y. Aihara and N. Chatani, Chem. Commun., 2016, 52, 10129 DOI: 10.1039/C6CC05330K

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