Issue 77, 2016
From the journal:

Chemical Communications

Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst†

Raja Pal,‡a   Joseph A. Laureanti,‡a   Thomas L. Groy,a   Anne K. Jones*a  and  Ryan J. Trovitch*a  

* Corresponding authors

a School of Molecular Sciences, Arizona State University, Tempe, Arizona 85287, USA
E-mail: anne.katherine.jones@asu.edu, ryan.trovitch@asu.edu
Tel: +1 480 727 8930

Abstract

In 5.0 M H2O/acetonitrile, [(Ph2PPrPDI)MoO][PF6]2 produces H2 with 96% Faradaic efficiency at −2.5 V vs. Fc+/0 and a rate of 55 s−1. Reactivity studies and isolation of a Mo(II) oxo intermediate, (Ph2PPrPDI)MoO, shed light on the H2 evolution mechanism.

Graphical abstract: Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

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Article information

DOI
https://doi.org/10.1039/C6CC04946J
Article type
Communication
Submitted
14 Jun 2016
Accepted
28 Aug 2016
First published
30 Aug 2016

Chem. Commun., 2016,52, 11555-11558

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Hydrogen production from water using a bis(imino)pyridine molybdenum electrocatalyst

R. Pal, J. A. Laureanti, T. L. Groy, A. K. Jones and R. J. Trovitch, Chem. Commun., 2016, 52, 11555 DOI: 10.1039/C6CC04946J

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